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Parylene AF4 (CAS No. 3345-29-7)

Basic information:

Product Name: 2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene
Synonyms:

1,1,2,2,9,9,10,10-Octafluoro[2.2]paracyclophane;Tricyclo[8.2.2.24,7]

hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro-;2,2,3,3,8,8,9,9-Octa;PARYLENE HT;Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, 2,2,3,3,8,8,9,9-octafluoro Tricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene, octafluoro;parylene AF4(parylene HT);2,2,3,3,8,8,9,9-Octafluorotricyclo[8.2.2.24,7]hexadeca-4,6,10,12,13,15-hexaene;Parylene-AF4

CAS: 3345-29-7
MF: C16H8F8
MW: 352.22

Chemical properties:

Melting point 240-250°C
Boiling point 259.3±40.0 °C(Predicted)
density 1.47±0.1 g/cm3(Predicted)
form powder

    product details

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    7 Jan 2019
    Parylene finds widespread use in various applications like aerospace, automotive, medical, semiconductor, and electric. It is a polymer that is best-suited for conformal coatings because of its inert nature. Parylene is an excellent barrier coating, and therefore, it has rapidly found use in tiny coating parts, for example, circuit board components.
    Parylene AF-4 is the only parylene type that displays a consistent degree of UV-resistance, one wherein performance is maintained relatively long-term. Like the other parylene types, AF-4 also forms an effective, structurally continuous protective film as thin as several hundred angstroms, due to uniqueness of the chemical vapor deposition (CVD) process used to coat substrate surfaces.
    Also called aliphatic fluorinate, AF-4 replaces the alpha hydrogen atom of the N dimer with fluorine, and totals 4 atoms. This compositional variation allows AF-4 to generate the lowest parylene coefficient of friction and dielectric constant throughout UV-exposure, and the highest penetrating ability. AF-4 is also useful in high temperature, short-term applications up to 450°C.
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    Characteristics of Parylen AF4 coating

    7 Jan 2019
    Specialties:
    Unmatched UV stability
    Excellent thermal stability at high service temperature (350)
    Unmatched oxidation stability
    Completely conformal coating
    Superior crevice penetration, pin hole free
    Anti-saline damage
    Anti-stick ion
    Barrier properties:
    Chemical insolubility and solvent resistant
    Low water absorption
    Hydrophobic properties
    Low gas permeability , no out-gassing
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    Physical & mechanical properties:
    Transparent
    Light-weight and ultra-thin
    Low CTE
    Low coefficient of friction
    Good dry lubricity
    Abrasion resistance
    Stabilization of components and structures
    Particulate immobilization
    Electrical properties:
    Electrical insulation
    High dielectric strength
    High volume resistivity ,ohm-cm
    Low dissipation factor
    Low dielectric constant
    Mitigation of tin whisker growth
    Biocompatibility and bio-stability
    USP class VI
    Microorganism resistance
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    Application

    7 Jan 2019
    Parylen AF4 is extremely useful in high temperature applications and those in which long-term UV stability is required.
    Aerospace
    Military
    Electronic
    Medical
    Industrial
    Semiconductor (3D IC TSV electrical insulation , AMOLED De-bonding layer , Barrier layer )
    Bio-MEMS electrode protection film
    EWD (Electro Wetting Device) Liquid lens
    Parylene AF4 Polymer is superior to most liquid-based coatings like acrylic or silicone. The parylene is an excellent coating for protecting aerospace PCBs and many other electronic components and assemblies. The encapsulation conforms amazingly on all kinds of device surfaces, including edged services, complex creviced services, flat or round surfaces. Another plus point of the polymer is that the coating does not increase the weight of the coated device in anyways.

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